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is accompanied by charge transfer from B to A. Most chemical reactions are initiated by an interaction of this type between an occupied molecular orbital of one molecule and a virtual molecular orbital of another. Figure 3.9a may also represent the interaction of a nonbonded (``lone-pair'') orbital with an adjacent polar p or s bond [67]. If a polar p bond, one can explain stabilization of a carbanionic center by an ``electron-withdrawing'' substituent (C O), or the special properties of the amide group. If a polar s bond, we have the origin of the anomeric e ect. The interaction is accompanied by charge transfer from B to A, an increase in the ionization potential, and a decreased Lewis basicity and acidity. These consequences of the two-electron, two-orbital interaction are discussed in greater detail in subsequent chapters. If Figure 3.9a represents bond formation between two molecules, the reverse process would correspond to heterolytic bond cleavage. One notes, however, that in the gas phase heterolytic bond cleavage is never observed. As we shall see, the interaction depicted in Figure 3.9a is the primary interaction between any pair of molecules whether it leads to bond formation or not. It is responsible for van der Waals attraction and hydrogen bonding. Figure 3.9b portrays homolytic bond formation by the recombination of radicals and is accompanied by charge transfer from A to B. The radicals must be singlet coupled. The interaction of triplet-coupled electron pairs is repulsive and does not lead to bond formation. The reverse process describes homolytic bond cleavage and results in singletcoupled free radicals.

(5.160)

The size and scope of your organization should be accurately reflected in the look of your Web site If you are the regional chapter of a large national organization, your Web site should have a more official look that includes some visual element on your homepage that indicates this perhaps a map or recognizable regional symbol If you are a community-based, local organization, your homepage should include design elements that reflect the local community local landmarks or symbols and a more friendly, people-oriented look A note here it is almost always money well spent to hire a professional design firm to develop the look and feel of your homepage, rather than relying on in-house nonspecialized staff The second consideration in branding your organization online should be looking at the language and choice of content you have on your homepage.

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and locate a page that contains installation instructions. Then copy the URL and paste it into the Page field. (Or add the URL to the Externals tab and link to it.) The HTML this option writes is pluginspage= url.com/thepage .

Elapsed time (s)

How do you want to engage your visitors If your organization provides primary information and reference services, then your homepage should be organized to facilitate access to your information, and should use a tone and vocabulary that is in line with an information-oriented service (see Exhibit 61)..

The last integral is zero because of the orthogonality of the unperturbed wave functions. Equation (A.101) simpli es to

Figure 21.12 Three tasks (upper right, heavy green lines) of the Data Grid during disaster recovery when either a PACS server or the SAN fails. Site 3 is used as an example. Task 1: Allow site 3 PACS WS to Q/R its own images from the Data Grid for continuing clinical operation. Task 2: After its server and SAN have been restored, the Data Grid rebuilds P1 of SAN 3 installing its own images. Task 3: After its server and SAN have been restored, the Data Grid rebuilds P2 of SAN 3, which has the backup images of other PAC systems connected to the Data Grid. All three tasks are performed without human intervention. Work ows and operations of Figures 21.10, and 21.11A and B allow the Data Grid to automatically complete the three tasks.

Without some explanation and discussion, much of what s in Table 9-1 makes sense only to those who already know a lot about how graphics are handled in Windows, and how TV signals are captured, manipulated, and displayed on various devices. We dig into these topics next, matching entries from the table to subsection headings to drive our coverage of what s really going on inside Table 9-1 and what it means to you and your HTPC.

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